The Department of Mathematics was established in 1929 at the intermediate level and was elevated to a degree-level program in 1952. Presently, the department offers a B.Sc. undergraduate course, operating effectively in accordance with the guidelines of Dr. Babasaheb Ambedkar Marathwada University, Chhatrapati Sambhajinagar.

Over the years, the department has been led by several distinguished academicians, including Dr. D. B. Muley (Former Director, Institute of Science, Chhatrapati Sambhajinagar and Nagpur), Dr. Chine, Dr. S. G. Pohnerkar (Former Principal of the College and Former Joint Director, Chhatrapati Sambhajinagar), Shri S. G. Shastri, Shri G. L. Waghmare, Smt. Usha S. Mulay, Dr. R. M. Lahurikar, Dr. S. A. Morye, and Dr. A. V. Sonawane, who has been serving as the Head of the Department since August 2021.